CHEM 3II3
INTRODUCTION TO TRANSITION METAL CHEMISTRY
Fall 2026 · Intro: Transition Metal Chem · C01
Readings
- eText Inorganic Chemistry - 6 Month Access Ed: 8ISBN 9780192636744; 9780198866916
Fall 2026 · Draft · C01
Topics
- Electronic configuration for metals and their complexes
- General trends: atomic radii, ionic radii, ionisation energies
- Physical properties, basic chemical properties, oxidation state trends (Frost diagrams)
- Historical introduction – Werner vs. Blømstrand theories, definitions and IUPAC nomenclature
- Coordination number and geometry
- Types of ligand: bridging and chelating (monodentate, bidentate, polydentate etc.)
- Types of isomerism: geometric ( cis , trans , mer , fac ), optical, ionization, linkage, coordination
- Thermodynamics: equilibrium constants, formation constants {stepwise (K), overall (b)}, chelate and macrocycle effects, Irving-Williams series
- Organic ligands
- Organometallic species
- Crystalline lattices – how crystal field theory came about
- Octahedral CF splitting diagram
- Crystal field splitting energy (CFSE), spectrochemical series for ligands and metals
- Low spin and high spin complexes, explanation for trends in ionic radii
Readings
- Inorganic ChemistryOxford University Press · ISBN 9780198866916
- Inorganic Chemistry ISBN: 9780198866916 Authors: Mark Weller; Jonathan Rourke; Fraser Armstrong; Simon Lancaster; Tina Overton Publisher: Oxford University Press Publication Date: 2025 Edition: 8th The textbook is recommended, not mandatory. The 7th edition is acceptable.
- The textbook is recommended, not mandatory. The 7th edition is acceptable.
Fall 2025 · Intro: Transition Metal Chem · C01
Readings
- Etext Inorganic Chemistry - 6 Month Access Ed: 8ISBN 9780192636744; 9780198866916
Sources
- Course catalogue ↗2026–2027
- Campus Store (short title) ↗
- Campus Store reading list ↗Fall 2026
- Course outline / syllabus ↗Fall 2026
- Campus Store reading list ↗Fall 2025