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CHEM 3II3

INTRODUCTION TO TRANSITION METAL CHEMISTRY

Undergraduate

Fall 2026 · Intro: Transition Metal Chem · C01

Readings

  • eText Inorganic Chemistry - 6 Month Access Ed: 8
    Weller · 8 · Suggested
    ISBN 9780192636744; 9780198866916
Fall 2026 · Draft · C01

Topics

  • Electronic configuration for metals and their complexes
  • General trends: atomic radii, ionic radii, ionisation energies
  • Physical properties, basic chemical properties, oxidation state trends (Frost diagrams)
  • Historical introduction – Werner vs. Blømstrand theories, definitions and IUPAC nomenclature
  • Coordination number and geometry
  • Types of ligand: bridging and chelating (monodentate, bidentate, polydentate etc.)
  • Types of isomerism: geometric ( cis , trans , mer , fac ), optical, ionization, linkage, coordination
  • Thermodynamics: equilibrium constants, formation constants {stepwise (K), overall (b)}, chelate and macrocycle effects, Irving-Williams series
  • Organic ligands
  • Organometallic species
  • Crystalline lattices – how crystal field theory came about
  • Octahedral CF splitting diagram
  • Crystal field splitting energy (CFSE), spectrochemical series for ligands and metals
  • Low spin and high spin complexes, explanation for trends in ionic radii

Readings

  • Inorganic Chemistry
    Mark Weller; Jonathan Rourke; Fraser Armstrong; Simon Lancaster; Tina Overton · 2025 · 8th · Recommended / optional
    Oxford University Press · ISBN 9780198866916
  • Inorganic Chemistry ISBN: 9780198866916 Authors: Mark Weller; Jonathan Rourke; Fraser Armstrong; Simon Lancaster; Tina Overton Publisher: Oxford University Press Publication Date: 2025 Edition: 8th The textbook is recommended, not mandatory. The 7th edition is acceptable.
    See source
  • The textbook is recommended, not mandatory. The 7th edition is acceptable.
    See source
Fall 2025 · Intro: Transition Metal Chem · C01

Readings

  • Etext Inorganic Chemistry - 6 Month Access Ed: 8
    Weller · 8 · Suggested
    ISBN 9780192636744; 9780198866916
Sources